Yes. You can set your Local Services Ads schedule to control when your ads are eligible to show, based on your business hours and when you want to receive leads. This can be useful if you only want leads when someone is available to answer the phone or respond to customers.
For example, an HVAC company might choose to show ads during the hours its team can quickly answer calls and schedule service. Keep in mind that limiting your ad schedule also limits the opportunities to receive leads. If customers commonly search for your services outside your selected hours, you could miss potential jobs.